I have a somewhat similar but slightly older machine, a Precision 7730 with Xeon E-2176M, 128GB ECC RAM, Quadro P3200 GPU. It's usually connected to a TB19 dock with either single or dual Thunderbolt, and I have my displays connected through the TB19 docks -- either dual 1920x1200 or 4K monitors, using a mix of HDMI and mDP. No issues with this setup as far as displays, with TBC or other applications. I'm not exactly sold on the Thunderbolt connection/dock though... it's got the bandwidth but there is a lot of additional downstream hardware in the mix that makes things more complicated and slightly more unstable. If you want a single plug-in for a dock that does everything it's your best bet though. Mine are generally good but do have the occasional hiccup.
In Win10 22H2 the setting for which GPU to use per-program is in Settings >> Display >> Graphics settings >> Graphics performance preference.
I am told the newer Precision laptops are a bit more stable hardware-wise than the older generations (specifically 7730). They get cranky with certain combinations of hardware and settings and like to start freezing and/or blue-screening.
There is the option in the BIOS to disable the integrated GPU and always use the discrete GPU (MUX switch), but I started having frequent issues with the USB bus on mine when I did that. If it's stable on your hardware that's the easiest way to force using dGPU for everything if that's what you want, though battery life will be abysmal if not docked. I did not see any noticeable performance degradation on my machine letting the dGPU mux back into the iGPU and only using dGPU for certain applications.
YMMV.